Valve block assembly for a bottle attachment apparatus

ABSTRACT

A valve block assembly for a bottle attachment apparatus for handling liquids has a valve block, an intake valve insert and/or an exhaust valve insert, and a valve receptacle assigned to the respective valve insert. The valve insert is inserted in a replaceable and sealing manner in the valve receptacle. The valve insert has a stop portion, a fastening portion distinct therefrom and a sealing portion distinct from both. The associated valve receptacle has stop, fastening, and sealing portions matching the equivalent portions of the valve insert. When the valve insert is installed correctly both the stop portions and the sealing portions bear on one another in a planar manner.

BACKGROUND OF THE INVENTION Field of the Invention

The invention relates to a valve block assembly for a bottle attachmentapparatus for handling liquids, and to a bottle attachment apparatus forhandling liquids comprising such a valve block assembly.

Description of Related Art

In the case of bottle attachment apparatuses for handling liquids, thefocus is on precisely measuring and conveying liquids from a storagebottle or another storage container, wherein precise measuring isperformed when a partial volume of liquid is received from the storagebottle or similar into the apparatus and/or when a partial volume ofliquid is externally dispensed from the apparatus into a container.

Bottle attachment apparatuses of the type being discussed are inparticular bottle attachment dispensers and burets. Bottle attachmentapparatuses of this type are widely used in chemical, biological, andpharmaceutical laboratories and production facilities.

The term “liquid” in the present context preferably refers to liquids asare used in chemical, biological, and pharmaceutical laboratories andproduction facilities etc. These are preferably liquids having arelative viscosity of up to about 300 (viscosity relative to theviscosity of water, measured at normal conditions). In colloquial terms,the liquids are thus preferably those in the range of very low viscosityto slightly viscous.

In the case of bottle attachment apparatuses of the type beingdiscussed, high requirements are set for volume accuracy of liquidintake and/or liquid dispensation, and for operator safety. The bottleattachment apparatuses are usually operated manually or else are drivenby an actuator.

A typical example of a bottle attachment apparatus in the form of abottle attachment dispenser is known from European Patent Application EP0 542 241 A2. The present invention proceeds from this prior art. Forbottle attachment apparatuses in the form of bottle attachmentdispensers, the entire content of European Patent Application EP 0 542241 A2 being incorporated herein by reference.

In an exemplary manner, a bottle attachment apparatus in the form of aburette is known from European Patent Application EP 2 799 141 A2 andcorresponding U.S. Pat. No. 8,142,738 B2. A bottle attachment apparatusin the form of buret has many construction details in common with abottle attachment apparatus in the form of a bottle attachmentdispenser. Also to this extent, the entire content of European PatentApplication EP 2 799 141 A2 and corresponding U.S. Pat. No. 8,142,738 B2is incorporated herein by reference.

Here and hereunder, a bottle attachment apparatus is always described inthe operating position thereof, that is to say in the position thereofwhen fastened to a storage bottle or similar, and when aligned in asubstantially vertical manner. A valve block assembly for such a bottleattachment apparatus is also described in a corresponding manner, thatis to say likewise in the operating position thereof, that is to saywhen installed in a bottle attachment apparatus which is in theoperating position thereof.

A substantial component part of a bottle attachment apparatus of thetype being discussed is the cylinder-and-piston assembly with the aid ofwhich the liquid may be suctioned and exhausted again. Saidcylinder-and-piston assembly has a cylinder which defines a longitudinaldirection, and a piston which is guided in a sealed manner in thecylinder so as to be longitudinally displaceable. In the event of anupward movement of the piston in the cylinder, the liquid is suctionedby forming negative pressure in the cylinder. In the event of a downwardmovement, the liquid in the cylinder is exhausted again from thecylinder. The flow of the liquid during suctioning, on the one hand, andduring exhausting, on the other hand, is directed by valves of the valveblock assembly. The cylinder-and-piston assembly is connected in asealing manner to the valve block assembly and to the lines which arelocated therein. The valve block assembly per se in turn is attachedonto the storage bottle or similar with the aid of the fasteningassembly.

An intake valve which allows liquid to be suctioned from the storagebottle by means of an intake pipe is located in the valve block of thevalve block assembly. The intake pipe, most often in the form of aplug-fitted tube, extends deeply downward into the storage bottle. Anexhaust line extends away from the valve block in an approximatelyhorizontal manner. An exhaust valve sits in the exhaust line or in thevalve block, so as to be at the beginning of the exhaust line. In someinstances, the exhaust line has an additional switching valve by way ofwhich a return flow line leading back into the storage bottle may beopened or closed. At an opening from which the liquid exits, the exhaustline may have a closure.

Since the exhaust line protrudes from the valve block in anapproximately horizontal manner and often also the previously discussedswitching valve sits there, this is that side from which an operatorworks on the bottle attachment apparatus. This side may be referred toas the “front side” of the bottle attachment apparatus. The oppositeside is the “rear side” of the bottle attachment apparatus. In the caseof an electronic design embodiment of a bottle attachment apparatus, adisplay having corresponding operator elements is preferably located onthe front side of the bottle attachment apparatus.

The fastening assembly for fastening the external housing and/or thevalve block assembly of the bottle attachment apparatus onto a storagebottle or similar is often a thread assembly which is similar to a unionnut, or is an internal thread which is incorporated into the valve blockper se, for screwing onto the external thread on a bottleneck of thestorage bottle (see the prior art mentioned at the outset). However, inprinciple other fastening assemblies, such as bayonet systems orshort-stroke collets are likewise employable, as are systems of the typeof a taper-ground joint, which are usual in laboratories.

The focus is presently on the valve block assembly for a bottleattachment apparatus of the type being discussed, and in particular onthe arrangement of the intake valve and/or the exhaust valve in thevalve block of the valve block assembly.

In the prior art from which the invention proceeds, and in many otherbottle attachment apparatus (European Patent Application EP 0 542 241A2, European Patent Application EP 2 799 141 A2 which corresponds toU.S. Pat. No. 8,142,738 B2, and German Patent Application DE 32 08 436A1 which corresponds to U.S. Pat. No. 4,526,924), the intake valve andthe exhaust valve are in each case embodied as discrete inserts, that isto say as intake valve insert or exhaust valve insert, respectively. Thevalve block has a valve receptacle assigned to each valve insert, thevalve insert being inserted in the former in a sealing and replaceablemanner.

In the prior art there are constructions of the valve block of the valveblock assembly of the bottle attachment apparatus, in which the intakevalve insert and the exhaust valve insert are constructed and insertedin the valve block in an identical manner. However, there are alsoconstructions in which a specific solution in terms of construction hasbeen chosen for the intake valve insert, but another solution in termsof construction has been implemented for the exhaust valve or for theexhaust valve insert.

The teaching of the invention relates to a bottle attachment apparatusand to a valve block assembly for such a bottle attachment apparatus tothe extent that at least one of the two valves is concerned, wherein theteaching is destined and suitable preferably for the design of bothvalves.

The arrangement of the respective valve in a valve insert which isreplaceable has obvious advantages in terms of handling and repair. Inthe prior art from which the invention proceeds, both the valve insertas well as the valve receptacle are designed in a cylindrical manner,and the valve insert is plugged into the valve receptacle in a tautmanner, down to the base of the valve receptacle. The base of the valvereceptacle and the end side of the cylindrical valve insert form stopportions which are assigned to one another. The stop portions run in atransverse manner to a longitudinal axis which is defined by the valveinsert having the associated valve receptacle.

The stop portions of the valve insert and of the valve receptacle, whichcome to bear on one another, simultaneously form an annular and planarsealing face for the valve insert. If and when the materials used in thevalve block, on the one hand, and in the valve insert, on the otherhand, are comparatively hard, and/or if and when the sealing faces aresomewhat non-planar, an additional annular seal is employed here in someinstances.

The cylindrical sleeve faces of the valve insert and of the valvereceptacle form the fastening portions, on the one hand, but also anencircling sealing face, on the other hand.

In other embodiments of bottle attachment apparatuses of the type beingdiscussed, the valve insert which is otherwise cylindrical is looselyplugged into the valve receptacle which is otherwise cylindrical and isscrewed thereto by means of a screw connection.

In the case of a valve block assembly of a bottle attachment apparatusof the type being discussed, both the valve block as such as well as thevalve insert are typically composed of plastics which are suitable forautoclaving. For details of the plastics which are typically to beemployed here and which often have to meet special requirements in termsof their resistance to chemicals, reference may be made to the prior artmentioned above (European Patent Application EP 2 799 141 A2 andcorresponding U.S. Pat. No. 8,142,738 B2), on the one hand, and to thepertinent technical literature and to the general catalog of theapplicant (BRAND Gesamtkatalog [general catalog] 900 (June 2013), pages334-341), on the other hand.

In the case of a valve block assembly of a bottle attachment apparatusof the type being discussed, it is essential that both the valve blockas well as the valve insert are typically composed of plastics which aresuitable for autoclaving. During autoclaving the laboratory apparatusesare sterilized according to DIN EN 285 in autoclaves, using water vaporat a temperature of 121° C.

The plastics which are typically to be employed here are plastically,that is to say permanently deformed during autoclaving, provided thatsaid plastics are under compressive stress. Said plastics only containresidual elasticity. If it is to be avoided that a bottle attachmentapparatus post-autoclaving becomes more or less leaky in places, thevalve insert has to be removed from the valve receptacle or at leastreleased therein prior to autoclaving.

If the measure outlined above is neglected during autoclaving, a valveblock assembly of the type being discussed will be unfit for use at thelatest after multiple autoclaving.

The teaching is based on the issue of stating a valve block assembly fora bottle attachment apparatus for handling liquids, which has improvedsealing in relation to the valve insert.

SUMMARY OF THE INVENTION

The present invention relates to a valve block assembly for a bottleattachment apparatus for handling liquids, wherein the bottle attachmentapparatus has a cylinder-and-piston assembly for suctioning andexhausting liquid, a valve block assembly, optionally an externalhousing receiving the valve block assembly, and a fastening assembly forfastening the external housing and/or the valve block assembly on astorage bottle or the like, wherein the valve block assembly has a valveblock, an intake valve insert, and/or an exhaust valve insert, whereinthe valve block has a valve receptacle which is assigned to therespective valve insert, wherein the valve insert is inserted in areplaceable and sealing manner in the valve receptacle, wherein thevalve block as well as the valve insert or the valve inserts,respectively, are composed of plastics which are suitable forautoclaving, wherein the valve insert has a stop portion, a fasteningportion which is distinct therefrom, and a sealing portion which isdistinct from both, wherein the associated valve receptacle has stop,fastening, and sealing portions matching the portions of the valveinsert, and wherein the fastening portions in the case of a valve insertwhich is installed in a functionally correct manner are inforce-transmitting mutual engagement in such a manner that both the stopportions as well as the sealing portions bear on one another in a planarmanner.

It is in particular possible for autoclaving to be performed withoutmanipulation of the valve insert or of the valve inserts, respectively,without the functional capability of the valve block assembly beingsubsequently compromised.

The teaching of the invention will hereunder be explained by means of avalve block assembly having a valve block, in conjunction with a valveinsert in a valve receptacle, preferably the intake valve insert in theintake valve receptacle. Moreover, however, the explanation also appliesin particular to a valve block assembly in which the constructionaccording to the invention has been implemented both for the intakevalve insert as well as for the exhaust valve insert.

It is initially relevant according to the invention that the valveinsert has a stop portion, and the valve receptacle likewise has amatching stop portion, as is present to this extent in the prior art. Itis likewise provided as in the prior art that the valve insert has afastening portion which is distinct from the stop portion, and the valvereceptacle has a matching fastening portion. In the prior art, thefastening portion on the valve insert in the case of a valve insertwhich is inserted by press-fitting is the cylindrical sleeve face, orthe external thread disposed on the cylinder sleeve, which engages withthe internal thread on the internal wall of the valve receptacle,respectively.

According to the invention, however, the stop portion and the fasteningportion are now supplemented on the valve insert by a sealing portionwhich is distinct from both the former. As opposed to the prior art inwhich the end-side stop portion achieves the sealing effect of the valveinsert in the valve receptacle, the sealing effect in the case of thevalve block assembly according to the invention is substantiallyachieved by means of the distinct sealing portions.

In the case of a valve insert which is installed in a functionallycorrect manner, the fastening portions of the valve insert and of thevalve receptacle are in force-transmitting mutual engagement in such amanner that both the stop portions as well as the sealing portions bearon one another in a planar manner.

Minimal static redundant dimensioning on account of the stop portions inconjunction with the sealing portions is utilized according to theinvention. The sealing portions, when bearing on one another, aredeformed for so long and thus in only a minimal manner, until the stopportions also bear on one another.

The stop portions typically run so as to be perpendicular to thelongitudinal axis which is defined by the valve insert and theassociated valve receptacle. Said stop portions may also run so as toslightly deviate from the right angle in relation to the longitudinalaxis. To this extent, a deviation of 10° in relation to the right angleshould preferably not be exceeded.

According to the invention, there is no additional sealing element onthe stop portions, the stop portions bearing on one another in a planarmanner. Mutual contact between the stop portions predefines the fixedpoint when inserting the valve insert into the valve receptacle. Thedimensions of the valve insert and of the valve receptacle are set suchthat in this state the sealing portions also bear on one another in aplanar manner. On account thereof, a large sealing face in the directionof the longitudinal axis results.

The valve block assembly according to the invention guarantees areliable sealing function at a low compression force which is to beapplied by the fastening portions, wherein additional sealing may bedispensed with. In particular, in the case of the construction accordingto the invention it is not required that the valve insert is removed orreleased prior to autoclaving. Distributing the functions acrossdistinct portions leads to the degrees of freedom required for beingable to consider deformation of the plastics during autoclaving.

The preferred construction in the case of the valve block assemblyaccording to the invention is such that the stop portion on the valveinsert is disposed on the front end of the valve insert, which end islocated in the valve receptacle, that the sealing portion is disposed inthe direction of the opposite, rear end of the valve insert, adjoiningthe stop portion, and that the fastening portion is disposed in thedirection of the rear end of the valve insert, adjoining the sealingportion.

As an alternative, the stop portion on the valve insert may be also bemoved so as to be between the sealing portion and the fastening portion,or even so as to be entirely up front, even ahead of the fasteningportion. However, the previously mentioned variant has the advantagethat the stop portions which bear on one another in a planar manneralready fulfill a sealing function.

The indication of a portion being disposed so as to “adjoin” anotherportion may preferably mean that they are directly adjoining. However,this indication is not limited to this understanding. In principle, itis also possible for certain spacings to be present between theportions, in a certain sense thus “intermediate portions”, which areirrelevant to the functioning of the valve block assembly according tothe invention in the context of the invention.

A statement regarding the orientation of the stop portions has alreadybeen made above. There is also a preferred arrangement for orienting thesealing portions, having as a reference again the longitudinal axiswhich is defined by the valve insert and by the associated valvereceptacle. To this extent, it is recommended that the sealing portionsare aligned at an acute angle in relation to the longitudinal axis,preferably at an angle between 1° and 20°, and particularly preferablyat an angle between 2° and 10° in relation to the longitudinal axis. Thesealing portions thus do not run parallel with the longitudinal axis, sothat the compression force which is relevant to the sealing effect maybe only radially aligned, but the former run so as to be slightlyinclined in relation to the longitudinal axis. On account thereof, anadequate radial effect of force on the sealing portions may beimplemented by a force component which acts in the direction of thelongitudinal axis. In this way, the sealing portions acquire theiroptimum sealing effect, while radial compression of the plasticsmaterial in the sealing portions is limited on account of the stopeffect thereof by the stop portions.

Proceeding from one preferred variant having a valve insert which inrelation to the longitudinal axis is rotation-symmetrical, the sealingportions in the above-discussed concept are configured in atruncated-cone shape.

However, in principle the valve insert and the associated valvereceptacle may also be embodied so as not to be rotation-symmetrical;this would lead to a prismatic design of the sealing portions.

According to one further preferred construction variant it may beprovided that the angle of the sealing portion on the valve receptaclein relation to the longitudinal axis is up to 2.5° larger than the angleof the sealing portion on the valve insert in relation to thelongitudinal axis. In this way, the sealing portion on the valve insertinitially touches the sealing portion on the valve receptacle only byway of linear contact. If force is exerted by the fastening portions inthe direction of the longitudinal axis, the linear contact by way ofdeformation of the sealing portions is transformed into a planarcontact. In the course of time, accelerated in particular by hightemperatures as in autoclaving, successive completion of the planarcontact and thus reliable sealing across the sealing portions isperformed.

The term “bearing on one another in a planar manner” thus does not meanthat the sealing portions bear on one another across the full area fromthe outset. Rather, the extent of the faces of the sealing portionswhich bear on one another may be enlarged under the influence ofpressure and temperature, until bearing of the sealing portions on oneanother across the entire area is achieved.

In a further teaching of the invention, which is independent as such andwhich is of independent relevance, the issue has been solved in that thevalve insert has a fastening portion and a sealing portion which isdistinct therefrom, that the associated valve receptacle has fasteningand sealing portions matching the portions of the valve insert, that thefastening portions in the case of a valve insert which is installed in afunctionally correct manner are in force-transmitting mutual engagementin such a manner that the sealing portions bear on one another in aplanar manner, that the valve insert and the associated valve receptacledefine a longitudinal axis, and that the sealing portions are aligned atan acute angle in relation to the longitudinal axis, preferably at anangle between 1° and 20°, in particular between 2° and 10° in relationto the longitudinal axis. Stop portions are dispensed with here. In anycase, respective designs on the valve block assembly are not utilizedfor stop purposes. The mutually interacting sealing portions which arealigned at an acute angle to the longitudinal axis as such also effectdelimitation of the movement path of the valve insert into the valvereceptacle, expediently by means of a correspondingly limitedapplication of force across the fastening regions.

It preferably also applies to the construction that the sealing portionsare configured in a truncated-cone-shape, assuming arotation-symmetrical valve insert, or are designed to be prismatic,assuming a valve inset which is embodied so as not to berotation-symmetrical.

Further preferred designs and refinements relate to the constructivedesign of the walls of the valve block and of the valve insert in theregion of the sealing portions.

In as far as the manufacture of the valve block and of the valve insertsis concerned, manufacturing in the plastics injection molding method isrecommended. Fluoropolymers may be employed in an exemplary manner forthe valve block and for the valve insert.

The construction of the valve block assembly according to the inventionis of particular interest if the plastics of the mutually interactingcomponents are selected and mutually adapted so as to guarantee targeteddeformation of the mutually interacting components on the faces whichcome to bear on one another. To this extent it has proven expedient forboth the plastics of the valve block as well as the plastics of thevalve insert to have a tensile strength in excess of 12 MPa at 120° C.(EN ISO 12086). It is particularly preferable here for the plastics ofthe valve block to have a tensile strength (EN ISO 12086, measured at23° C.) which is higher by 40% to 100% than the plastics of the valveinsert. To this end examples will be illustrated in the special part ofthe description (description of the figures).

Up to this point with reference to the teaching of the invention, nofurther discussion pertaining to the design embodiment of the fasteningportions has taken place. It is recommended that the fastening portionsare designed such that a defined effect of force may be achieved. Here,the design embodiment of the fastening portions as mutually engagingscrew thread portions is particularly preferable. A bayonet connection,a short-stroke clamping connection, or a stopper-type connection arealso possible. However, the design embodiment of the fastening portionsas a screw connection allows the valve insert to be inserted into thevalve receptacle in a particularly sensitive manner, up to the stop ofthe stop portions which is clearly perceivable during screwing-in, or upto a specific limiting force being readied or exceeded, respectively.The latter may be implemented using a torque tool by way of which thevalve insert is screwed or turned into the valve receptacle,respectively.

According to the invention, a push-fit connector for a tube or anothertype of intake line which reaches into the storage bottle may bearranged on the valve insert of the intake valve, and be preferablymolded thereon in an integral manner. In a further improvement thepush-fit connector close to the intake valve insert is surrounded by asupport collar of the intake valve insert, which is spaced apart by anencircling gap, and even further the push-fit connector and optionallyalso the support collar is/are integrally molded on the intake valveinsert.

The subject matter of the invention is not only the afore-describedvalve block assembly for a bottle attachment apparatus for handlingliquids, but also and in particular a bottle attachment apparatus forhandling liquids, the valve block assembly of which is designed in themanner discussed above.

In particular the invention relates to a bottle attachment apparatus forhandling liquids having a cylinder-and-piston assembly for suctioningand exhausting liquid, a valve block assembly, optionally an externalhousing receiving the valve block assembly, and a fastening assembly forfastening the external housing and/or the valve block assembly on astorage bottle or the like, wherein the valve block assembly has a valveblock, an intake valve insert, and/or an exhaust valve insert, whereinthe valve block has a valve receptacle which is assigned to therespective valve insert, wherein the valve insert is inserted in areplaceable and sealing manner in the valve receptacle, wherein thevalve block as well as the valve insert or the valve inserts,respectively, are composed of plastics which are suitable forautoclaving, wherein the valve insert has a stop portion, a fasteningportion which is distinct therefrom, and a sealing portion which isdistinct from both, wherein the associated valve receptacle has stop,fastening, and sealing portions matching the portions of the valveinsert, and wherein the fastening portions in the case of a valve insertwhich is installed in a functionally correct manner are inforce-transmitting mutual engagement in such a manner that both the stopportions as well as the sealing portions bear on one another in a planarmanner.

The invention further relates to a bottle attachment apparatus forhandling liquids having a cylinder-and-piston assembly for suctioningand exhausting liquid, a valve block assembly, optionally an externalhousing receiving the valve block assembly, and a fastening assembly forfastening the external housing and/or the valve block assembly on astorage bottle or the like, wherein the valve block assembly has a valveblock, an intake valve insert, and/or an exhaust valve insert, whereinthe valve block assembly has a valve block, an intake valve insert,and/or an exhaust valve insert, wherein the valve block has a valvereceptacle which is assigned to the respective valve insert, wherein thevalve insert is inserted in a replaceable and sealing manner in thevalve receptacle, and wherein the valve block as well as the valveinsert or the valve inserts, respectively, are composed of plasticswhich are suitable for autoclaving, wherein the valve insert has afastening portion and a sealing portion which is distinct therefrom,wherein the associated valve receptacle has fastening and sealingportions matching the portions of the valve insert, the fasteningportions in the case of a valve insert which is installed in afunctionally correct manner are in force-transmitting mutual engagementin such a manner that the sealing portions bear on one another in aplanar manner, the valve insert and the associated valve receptacledefine a longitudinal axis, and that the sealing portions are aligned atan acute angle in relation to the longitudinal axis.

All other aspects of the valve block assembly as such can be employedwith a valve block assembly in a bottle attachment apparatus as well.

The invention will be explained in more detail in the following withreference to the accompanying drawings which merely illustrates apreferred exemplary embodiment:

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a bottle attachment apparatus for handling liquids, in theform of a bottle top dispenser, in a perspective view;

FIG. 2 shows the bottle attachment apparatus from FIG. 1, but without aswitching valve in the exhaust line, in a perspective view;

FIG. 3 shows the bottle attachment apparatus of FIG. 1 in a section inthe region of the valve block assembly;

FIG. 4a shows the valve block assembly of the bottle attachmentapparatus from FIG. 3, in a detail in the region of the intake valveinsert;

FIG. 4b shows a valve block assembly of a further exemplary embodiment,in an illustration which corresponds to that of FIG. 4a ; and

FIG. 4c shows a valve block assembly of a further exemplary embodiment,in an illustration which corresponds to that of FIG. 4 a.

DETAILED DESCRIPTION OF THE INVENTION

FIGS. 1 and 2 show in each case a preferred exemplary embodiment of abottle attachment apparatus 1 according to the invention for handlingliquids, herein in the form of a bottle top dispenser.

In general terms, in respect of bottle attachment apparatuses forhandling liquids, i.e. so-called “liquid handling” apparatuses,reference may be made to the general catalog of the applicant (BRANDgeneral catalog 900 [June 2013]). Bottle attachment apparatuses of thetype being discussed are comprehensively explained therein in terms ofconstruction and application. Moreover, in respect of bottle attachmentapparatuses of the type being discussed, reference may also be made tothe sources of the prior art, as stated at the outset.

The definitions pertaining to top and bottom, and to front and rear,which have been stated at the outset of the description, apply to thebottle attachment apparatus which is described here in the preferredexemplary embodiment. The bottle attachment apparatus 1 will always bediscussed in the position which is illustrated in FIG. 1, so as to be ona storage bottle 2 as a preferred example of a storage container, evenwhen said bottle attachment apparatus is not shown in this position inthe individual illustrations.

During operation, the bottle attachment apparatus 1 which is illustratedin FIGS. 1 and 2 is attached to a storage bottle 2. More specifically,the bottle attachment apparatus 1 with the aid of a fastening assembly 3is attached to the bottleneck of the storage bottle 2. If the bottleneckof the storage bottle 2 has an external thread, the fastening assembly 3may be a type of annular cap having an internal thread, said annular capbeing attached at the bottom of the bottle attachment apparatus 1.However, the fastening assembly 3 may also be configured in the form ofa stopper-like plug assembly, or assume other shapes. It is onlyessential that the bottle attachment apparatus 1 by means of thefastening assembly 3 may be securely fastened to the storage bottle 2 orto any other matching storage container.

The cylinder-and-piston assembly 5 of the bottle attachment apparatus 1can be seen at the top of FIGS. 1 and 2. The bottle attachment apparatus1 presently has a cylinder-and-piston assembly 5 having an externalcylinder housing 5′ which encompasses the cylinder. A mechanical andadjustable stop for the length of the stroke is located on said cylinderhousing 5′.

A valve block assembly 4 supports the cylinder-and-piston assembly 5,but the former as such according to the preferred teaching here islocated in an external housing 6 of the bottle attachment apparatus 1,that is to say that said valve block assembly 4 is not directlyidentifiable in FIG. 1. The fastening assembly 3 per se is located onthe valve block assembly 4 or, as is the case here, on the externalhousing 6.

An exhaust line 7 forwardly protrudes from the external housing 6 of thebottle attachment apparatus 1, said exhaust line 7 in the illustratedexemplary embodiment being disposed and guided in a cantilever-typemount 8 which is of angular design. The exhaust line 7 terminates at atip 9. A mounting lug 10 which holds a closure cap 11, by way of whichthe mouth opening 9′ on the tip 9 may be closed off and protectedagainst dripping liquid, is fastened to the mount 8.

An intake line 12 for liquid extends downward from the valve blockassembly 4, which is hidden in the external housing 6, into the storagebottle 2. Besides the intake line 12, a return flow line 13 throughwhich the liquid may be directed back into the storage bottle 2 insteadof through the exhaust line 7, if required, can be seen in FIG. 1.

A switching valve 14 which is suitable for returning the flow of liquidinto the storage bottle 2 and which is actuatable by means of a toggle15 on the upper side of the mount 8, here is located outside the valveblock assembly 4 and outside the external housing 6, and in thepreferred exemplary embodiment illustrated in FIG. 1 is located withinthe mount 8 for the exhaust line 7.

FIG. 2 shows a bottle attachment apparatus 1 in the form of a bottleattachment dispenser without a switching valve 14, that is to saywithout the “return dosing” function, which is explained in detail inthe prior art (European Patent Application EP 0 542 241 A2). In thiscase, the return flow line 13 is of course also missing.

FIG. 3 shows the bottle attachment apparatus 1 of FIG. 1 in a sectionalview. The particular interest for the purpose of the present inventionis directed toward the valve block assembly 4 which here is identifiablein the external housing 6. The valve block assembly 4 is typicallycomposed of plastics, in particular of plastics resistant to chemicals.The valve block assembly 4 has a multiplicity of ducts and installedelements, for which reference in detail may be made to the prior artwhich has been discussed at the outset.

The valve block assembly 4 presently has a valve block 20, an intakevalve insert 21 a, and an exhaust valve insert 21 b. The system ofreference signs chosen here is related to the fact that hereunder onlyone valve insert 21 is discussed in an exemplary manner when describingthe exemplary embodiment. This valve insert 21 is indeed preferably theintake valve insert but may also be the exhaust valve insert. Both theintake valve insert 21 a as well as the exhaust valve insert 21 b arepreferably constructed and disposed in the manner which will bedescribed hereunder in detail.

The valve block 20 has a valve receptacle 22 which is assigned to thevalve intake 21. In the illustration in FIG. 3 there is thus an intakevalve receptacle 22 a and an exhaust valve receptacle 22 b, because thepreferred exemplary embodiment which as been shown to this extent hascorresponding inserts for both valves (this being understood so as notto limit the scope of the invention).

The intake valve insert 21 a is located in the downwardly orientedintake valve receptacle 22 a in the valve block 20, the intake line 12adjoining the former in a downward manner into the storage bottle 2.Toward the top, an intake duct 23, which leads to the cylinder of thecylinder-and-piston assembly 5, adjoins the intake valve receptacle 22 ain the valve block 20. An exhaust duct 24 in the valve block 20, whichis directed to the right in FIG. 3, branches off from the intake duct23, said exhaust duct 24 leading into the exhaust valve receptacle 22 bin which the exhaust valve insert 21 b is located.

In the preferred exemplary embodiment illustrated, the switching valve14 in the flow direction of the liquid is located behind the exhaustvalve insert 21 b. This may be readily seen in FIG. 3. However, thereare also solutions in terms of construction in which the sequence isreversed, that is to say that the switching valve in the flow directionis ahead of the exhaust valve.

For details of the valve block assembly 4 according to the invention,reference is now made to the enlarged illustration of details in FIG. 4a, which enables the construction of the valve block assembly accordingto the invention to be illustrated in more detail by means of theexample of the intake valve, which is however not to be understood asbeing limiting. FIGS. 4a and 4c show modified embodiments of the valveblock assembly 4, which are to be explained in more detail below.

FIG. 4a shows the valve insert 21 is inserted in a replaceable andsealing manner in the valve receptacle 22. A valve seat 21′ for a valvebody 21″ which here is embodied as a valve ball can be seen in the valveinsert 21. In the exemplary embodiment illustrated here and in theillustration of the valve insert 21 as an intake valve insert, the valveball which forms the valve body 21″ bears on the valve seat 21′ by wayof its own dead weight and, on account thereof, closes off the intakeline 12. There is thus no valve spring pressing the valve body 21″ ontothe valve seat 21′ provided here, as would be expediently provided inthe case of an exhaust valve insert.

A valve cage 21′″ which delimits the capacity of movement of the valvebody 21″ over an upward path is disposed in the valve insert 21. Thevalve cage 21′″ is preferably inserted in the valve insert 21 andfastened by means of a snap-hook structure. The valve cage 21′″ towardthe cylinder has a stop structure and laterally has a plurality of legsfor a valve body 21″. The legs serve as a lateral guide for the valvebody 21″. The space between the legs and between the valve body 21″ andthe valve insert 21 serves as a duct to enable the liquid to pass inthis way therethrough and therearound, respectively, in the present caseduring the intake stroke of the piston in the cylinder of thecylinder-and-piston assembly 5.

Both the valve block 20 and the valve insert 21 are, in each case,composed of plastics suitable for autoclaving at 121° C. As to detailspertaining to various plastics and the abbreviations thereof, referenceis made to the respective technical literature and to the generalcatalog of the applicant which has already been mentioned earlier.

The valve insert 21 has a stop portion 30, a fastening portion 31 whichis distinct therefrom, and a sealing portion 32 which is distinct fromboth. The valve receptacle 22 has a stop portion 30, fastening portion31, and sealing portion 32, all matching thereto.

As can be seen from FIG. 4a , the construction according to theinvention is such that in the case of a valve insert 21 which has beeninstalled in a functionally correct manner, the fastening portions 31are in force-transmitting mutual engagement in such a manner that boththe stop portions 30 as well as the sealing portions 32 bear on oneanother in a planar manner. On account thereof, a large wide sealingface, which is added to by the sealing face provided by the stopportions 30 which bear on one another, results in the region of thesealing portions 32.

In the preferred exemplary embodiment illustrated, the valve insert 21and the associated valve receptacle 22 define a longitudinal axis, andthe stop portions 30 run perpendicularly to this longitudinal axis. Thestop portions 30 thus have the optimal stop effect. An insertionmovement of the valve insert 21 performed in the direction of thelongitudinal axis is abruptly terminated when the stop portions 30 bearon one another.

It has already been pointed out in the general part of the descriptionthat the stop portions 30 may also be aligned so as to be slightlyinclined in relation to the longitudinal axis, the maximum angle ofinclination in relation to the perpendicular of the longitudinal axis tothis extent being preferably 10°.

As opposed to the prior art, the sealing function of the valve insert 21in the valve receptacle 22 has in any case been largely moved to thesealing portions 32. The sealing portions 32 in the case of a valveinsert 21 which has been installed in a functionally correct mannershould also bear on one another in a planar manner.

The preferred exemplary embodiment illustrated for the construction ofthe valve insert 21 shows that the stop portion on the valve insert 21is disposed on the front end of the valve insert 21, which end islocated in the valve receptacle 22, that the sealing portion 32 isdisposed in the direction of the opposite, rear end of the valve insert21, adjoining the stop portion 30, and that the fastening portion 31 isdisposed in the direction of the rear end of the valve insert 21,adjoining the sealing portion 32.

It has already been pointed out in the general part of the descriptionthat in principle a variant in which the stop portions 30 may bedisposed between the fastening portions 31 and the sealing portions 32,or may even be entirely disposed at the front end, even ahead of thefastening portions 31, may be chosen. However, in the construction whichis illustrated in FIG. 4a , the sealing effect of the stop portions 30,which is already present in the prior art, results, on account of whichthe sealing effect of the sealing portions 32 which are primarilyresponsible for sealing is supported.

The preferred exemplary embodiment illustrated furthermore displays aparticularly expedient construction in the form of the alignment of thesealing portions 32. The sealing effect is optimized in that the sealingportions 32 are aligned at an acute angle in relation to thelongitudinal axis, preferably at an angle between 1° and 20°,particularly preferably at an angle between 2° and 10°, in relation tothe longitudinal axis. While the stop portions 30 in the preferredexemplary embodiment illustrated are aligned so as to be exactlyperpendicular to the longitudinal axis of the valve insert 21, thesealing portions 32 are not aligned so as to be exactly parallel withthe longitudinal axis, but are at an acute angle thereto.

Assuming a rotation-symmetrical embodiment of the valve insert 21 and ofthe valve receptacle 22, this corresponding to a preferred construction,the above-described construction means that the sealing portions 32 areideally geometrically configured in a truncated-cone shape. A sealingportion which deviates therefrom and which has, for example, a sphericalface which is inclined at the stated angle seals at a similar contactpressure. The combination of dissimilar surfaces of the sealingportions, for example, with a planar face, on the one hand, and withproud annular structures, on the other hand, increases the sealingeffect.

The components which bear on one another are elastically and plasticallydeformed during autoclaving on the sealing portions 32 (typically byless than 1 mm, for example by about 0.4 mm) resulting in staticredundant dimensioning which, according to the invention, is utilized ina targeted manner for guaranteeing optimal sealing of the valve insert21 in the valve receptacle 22, even following a plurality of passesduring autoclaving.

The preferred exemplary embodiment illustrated in FIG. 4a on account ofthe scale does not let it be seen that according to a preferred teachingof the invention, the angle of the sealing portion 32 on the valvereceptacle 22 in relation to the longitudinal axis may be up to 2.5°larger than the angle of the sealing portion 32 on the valve insert 21.In this way, the sealing portion 32 on the valve insert 21 initiallytouches the sealing portion 32 on the valve receptacle 22 only by way oflinear contact. If force is exerted by the fastening portions 31 in thedirection of the longitudinal axis, the linear contact by way ofdeformation of the sealing portions 32 is transformed into a planarcontact. In the course of time, accelerated in particular by hightemperatures as in autoclaving, successive completion of the planarcontact and thus reliable sealing across the sealing portions 32 isperformed.

FIG. 4b shows a variant of the valve block assembly 4 from FIG. 4a , inwhich it is provided that the sealing portions 32 are disposed so as tobe substantially parallel with the longitudinal axis on the outer faceof the valve insert 21. Accordingly, the sealing portions 32 on thevalve receptacle 22 are also embodied so as to be substantiallycylindrical. Dimensioning of the valve insert 21 in the region of thesealing portions 21 is chosen such that a press-fit preferably resultswhen the former is inserted into the valve receptacle 22. On account ofthe effect of the fastening portions 31 which, as described, arepreferably embodied as mutually engaging screw thread portions, thevalve insert 21 is pushed into the valve receptacle 22, and the sealingportions 32, on account thereof, come to bear on one another in a planarmanner. The stop portions 30 delimit this push-fit movement. As isapparent from the sectional view in a plane extending along the lengthof the exhaust line 7 and valve receptacle 22 of FIG. 3, the intakevalve insert 21 a and the exhaust valve insert 21 b are sealed againstthe intake valve receptacle 22 a and exhaust, valve receptacle 22 b, bythe respective stop portions 30 and the sealing portions 32 without thepresence of any circumferentially elements.

The once again modified exemplary embodiment illustrated in FIG. 4c of avalve block assembly 4 according to the invention, has only fasteningportions 31 and sealing portions 32 which are distinct therefrom on thevalve insert 21 and on the valve receptacle 22. As is shown in FIG. 4c ,the sealing portions 32 here are at an acute angle in relation to thelongitudinal axis of the valve insert 21, preferably between 1° and 20°,particularly at an angle between 2° and 10°, in relation to thelongitudinal axis. The exemplary embodiment illustrated shows an angleof approx. 4°.

Since the fastening portions 31 in the illustrated exemplary embodimentare shown as screw thread portions, the sealing portions 32 must beconfigured to be truncated-cone-shaped. Reference may also be made hereto the considerations made above with regard to alternatives of thedesign of the sealing portions 32.

In the case of the construction shown in FIG. 4c , stop portions are notfunctionally essential. Rather, an obvious gap between the tip of thevalve insert 21 and the base of the valve receptacle 22 is visible.

FIG. 4a shows a further construction peculiarity of the preferredexemplary embodiment illustrated of a valve block assembly 4. It isspecifically provided here that the sealing portion 32 on the valvereceptacle 22 is configured on a wall 35 in the valve block 20, saidwall being here and preferably free-standing. In order for this to beachieved, a hollow chamber is located in the valve block 20, behind thewall 35. In the preferred exemplary embodiment illustrated, the wall 35has a uniform wall thickness, the latter preferably being 1 mm to 4 mm,in particular 2 mm, as is illustrated. There are no webs on the rearside of the wall 35; the wall 35 at the rear side is free-standing.This, on the one hand, guarantees a geometrically uniform sealingportion 32 and, on the other hand, results in uniform flexibility so asto achieve tuned deformation of the wall 35 and thus of the sealingportion 32 on the wall 35.

At another point, in particular on the exhaust valve insert 21 b, thefree-standing wall 35 may also be disposed externally on the valve block20.

A targeted design embodiment as on the valve block 20 is also providedaccording to a preferred teaching in a corresponding manner on the valveinsert 21. To this end, it is provided according to a preferred teachingthat the sealing portion 32 on the valve insert 21 is configured on awall 36 of the valve insert 21, said wall being here and preferablyfree-standing. The preferred exemplary embodiment illustrated shows thewall 36 of the valve insert 21 being graded, namely being somewhatthinner close to the stop portion 30 than close to the fastening portion31. However, overall attention has been paid to the thickness of thewall 36 of the valve insert 21 not being greater than the thickness ofthe wall 35 of the valve block 20 in the region of the sealing portions32.

As is already practiced in the prior art, it is particularly preferablyprovided according to the invention that both the valve block 20 as wellas the valve insert 21 are components which have been manufactured inthe plastics injection molding method. Typical examples of plasticswhich apart from polyolefins (for example: PP, PE) may be used includefluoropolymers such as PTFE, PCTFE, PFA, ETFE, FEP, or PVDF.

As has been repeatedly illustrated, the focus of the invention isselectively tuned deformation which is as slight as possible of thecomponents on the sealing portions 32. This is still to be so effectiveafter autoclaving or repeated autoclaving that sealing of the valveinsert 21 in the valve receptacle 22 is not compromised.

In order for the desired result according to the invention to beoptimized, a further preferred design embodiment which is characterizedin that both the plastics of the valve block 20 as well as the plasticsof the valve insert 21 have a tensile strength of in excess of 12 MPa at120° C. (EN ISO 12086) is recommended. The limit of the tensile strengthat 120° C. is intended to guarantee that adequate residual elasticity isretained even after repeated autoclaving. In conjunction with the smartarrangement of the sealing portions 32, the result according to theinvention is achieved in a particularly expedient manner.

Furthermore, an adapted pairing of materials for the plastics of thecomponents bearing on one another may be implemented. To this end it isrecommended that the plastics of the valve block 20 have a tensilestrength (EN ISO 12086, measured at 23° C.) which is higher by 40% to100% than the plastics of the valve insert 21. In one preferredexemplary embodiment which fulfils this construction specification, thevalve block 20 is composed of a fluoropolymer which has an elasticitymodulus of 500-1100 MPa at 23° C. (EN ISO 12086). A fluoropolymer whichhas an elasticity modulus of approx. 400-700 MPa at 23° C. (EN ISO12086) would then be a matching material for the valve insert 21.

It is achieved according to the invention that the valve block assembly4 does not need to be disassembled for autoclaving. The valve blockassembly 4 may be autoclaved on an as-is basis, without having to worryabout leakages on the valve inserts 21.

The preferred exemplary embodiments illustrated in FIGS. 4a, 4b , & 4 cshow that the fastening portions 31 are embodied as mutually engagingscrew thread portions. This is the preferred design embodiment whichenables particularly sensitive insertion of the valve insert 21 into thevalve receptacle 22. Alternatives include, for example, a bayonetconnection or a short-stroke collet. However, in terms of impinging thesealing portions 32 with force, these two alternatives are not asprecise as a thread connection.

Force-engaging elements to which a matching tool for performing thescrewing movements on the fastening portions 31 may be applied should belocated on the valve insert 21. More details pertaining thereto will beincluded herebelow in the context of the exemplary embodiment of FIG. 4c.

The exemplary embodiment illustrated in FIG. 4a also shows a particulardesign of the valve insert 21, the latter being an intake valve insert21 a in this case. In order for the intake line 12 to be attached, it isprovided that a push-fit connector 40 for a tube or the like is disposedat the rear end of the intake valve insert 21 a. According to a furtherpreferred and particularly expedient construction, it is provided thatthe push-fit connector 40 close to the intake valve insert 21 a issurrounded by a support collar 42 of the intake valve insert 21 a, whichby way of an encircling gap 41 is spaced apart. The support collar 42like the push-fit connector 40 is preferably integrally molded on thevalve insert 21.

It can be derived from FIG. 4a that the encircling gap 41 tapers off upto the base thereof. The wall of the push-fit connector 40 converselybecomes thicker. This is advantageous, since the intake line 12 in thestorage bottle 2 should protrude down to the base and is bent outward.In order for these bending forces to be absorbed, the thickness of thewall of the push-fit connector 40 is increased in a direction toward thetransition to the valve insert 21.

Furthermore, it may be derived from FIG. 4a that a tube which ispush-fitted onto the push-fit connector 40 and which forms the intakeline 12 into the storage bottle 2, by way of the frontmost portion ofsaid tube may be forced into the gap 41 where said tube then inconjunction with the push-fit connector 40 is jammed in a securelysealing manner by the support collar 42.

According to another further preferred teaching of the invention, aneven further portion which may be utilized for applying torque with theaid of a hand tool is provided on the valve insert 21, beside the stopportion 30, the fastening portion 31 which is distinct therefrom, andthe sealing portion 32 which is distinct from both the former. To thisextent, the valve insert 21 then has a total of four distinct portions.

In the modified exemplary embodiment of a valve block assembly 4according to the invention, which is illustrated in FIG. 4c , thesupport collar 42 of the valve insert 21 is utilized as a furtherportion for applying torque with the aid of a hand tool. Force-engagingelements 43, which are suitable for a hand tool and by way of whichtorque may be transmitted to the valve insert 21 and to the mutuallyengaged fastening portions 31, are molded on the external contour ofsaid support collar 42 which adjoins the lower end of the fasteningportion 31. These force-engaging elements 43 in FIG. 4b are illustratedas a radially molded toothing which may be readily manufactured in aplastics injection molded part.

A further portion for applying torque may be present on the valve insert21 in each of the exemplary embodiments described above. In particular,the support collar 42 of the valve insert 21 may be applied in each ofthe exemplary embodiments described above as a further portion forapplying torque.

It is derived from the entire illustration in the above explanationsthat the teaching of the invention relates not only to a valve blockassembly 4 for a bottle attachment apparatus 1 as a replacement part,but that the teaching of the invention very particularly also relates toa bottle attachment apparatus 1 in which a valve block assembly 4according to the invention is employed. To this extent, reference may bemade to the preceding explanations.

This description uses examples to disclose the invention including thebest mode enabling any person skilled in the art to make and use theinvention. The patentable scope of the invention, however, is defined bythe claims, and may include other examples that occur to those skilledin the art. Such other examples are intended to be within the scope ofthe claims if they have structural elements that do not differ from theliteral language of the claims, or if they include structural elementsequivalent to the structural elements covered by the literal language ofthe claims.

What is claimed is:
 1. A bottle attachment apparatus for handlingliquids, comprising: a cylinder-and-piston assembly for suctioning andexhausting liquid, a valve block assembly, and a fastening assembly forfastening the valve block assembly on a storage bottle, wherein thevalve block assembly has a valve block, an intake valve insert and anexhaust valve insert, wherein the valve block has an intake valvereceptacle which is assigned to the intake valve insert, wherein thevalve block has an exhaust valve receptacle which is assigned to theexhaust valve insert, wherein the intake valve insert is inserted in areplaceable and sealing manner in the intake valve receptacle, whereinthe exhaust valve insert is inserted in a replaceable and sealing mannerin the exhaust valve receptacle, wherein the valve block has an intakeduct which leads to a cylinder of the cylinder-and-piston assembly andconnects the cylinder and the intake valve receptacle, wherein the valveblock has an exhaust duct which leads to the cylinder of thecylinder-and-piston assembly and connects the cylinder and the exhaustvalve receptacle, wherein the valve block and each valve insert,respectively, are composed of plastic that is able to be used in anautoclave at a temperature of 121° C., wherein each valve insert has aplanar stop surface portion at an end face of the insert, a fasteningportion which is separated from the stop surface portion by an integralsealing surface portion which is distinct from both the stop portion andthe fastening portion, the integral sealing surface portion extendingperipherally around the valve insert adjacent to the stop portion at theend face and being planar when viewed in longitudinal cross section,wherein each valve receptacle has a planar stop surface portion, afastening portion, and a sealing surface portion matching the stopsurface portion, fastening portion, and sealing surface portion of therespective valve insert, wherein the respective duct and the stopsurface portion, sealing surface portion, and fastening portion of eachvalve receptacle are arranged successively in this order, and whereinthe fastening portions of each valve insert and the respective valvereceptacle, in an installed condition of the valve insert, are inforce-transmitting mutual engagement with each other in such a mannerthat both the stop surface portions and the sealing surface portions areforced into direct full face-to-face-abutment on one another over thefull surfaces thereof, the abutting surfaces of the stop surfaceextending in a planar manner perpendicular to the direction of thelongitudinal axis and the sealing surface portions extending at an acuteangle relative to a longitudinal axis of the insert.
 2. A bottleattachment apparatus for handling liquids, comprising: acylinder-and-piston assembly for suctioning and exhausting liquid, avalve block assembly, and a fastening assembly for fastening the valveblock assembly on a storage bottle, wherein the valve block assembly hasa valve block, an intake valve insert and an exhaust valve insert,wherein the valve block has an intake valve receptacle which is assignedto the intake valve insert, wherein the valve block has an exhaust valvereceptacle which is assigned to the exhaust valve insert, wherein theintake valve insert is inserted in a replaceable and sealing manner inthe intake valve receptacle, wherein the exhaust valve insert isinserted in a replaceable and sealing manner in the exhaust valvereceptacle, wherein the valve block has an intake duct which leads to acylinder of the cylinder-and-piston assembly and connects the cylinderand the intake valve receptacle, wherein the valve block and each valveinsert, respectively, are composed of plastic that is able to be used inan autoclave at a temperature of 121° C., wherein each valve insert andthe respective valve receptacle define a longitudinal axis, wherein eachvalve insert has a fastening portion and an integral sealing surfaceportion which is distinct from the fastening portion, the integralsealing surface portion extending peripherally around the valve insertadjacent to an end face of the valve insert, the sealing surface portionbeing planar when viewed in longitudinal cross section and extendingaway from said end face toward an opposite end of the valve insert at anacute angle in relation to said longitudinal axis, wherein each valvereceptacle has a fastening portion and an integral sealing surfaceportion, wherein the integral sealing surface portion of each valvereceptacle extending peripherally around the valve receptacle adjacentto an end face of the valve receptacle, the sealing surface portionbeing planar when viewed in longitudinal cross section and extendingaway from said end face toward an opposite end of the valve receptacleat an acute angle in relation to said longitudinal axis and matching thefastening portion and sealing surface portion of the respective valveinsert, wherein the fastening portion of each valve insert and thefastening portion of the respective valve receptacle, in an installedcondition of the valve insert, are in force-transmitting mutualengagement with each other in such a manner that the sealing surfaceportion of each valve insert and the sealing surface portion of therespective valve receptacle are forced into direct fullface-to-face-abutment on one another over the full surfaces thereof,wherein the sealing surface portion of each valve insert and the sealingsurface portion of the respective valve receptacle are aligned at saidacute angle in relation to the longitudinal axis, wherein the mutuallyinteracting sealing surface portions aligned at the acute angle inrelation to the longitudinal axis effect delimitation of the movementpath of each valve insert into the respective valve receptacle, andwherein the sealing surface portion of at least one of the valvereceptacles is configured on a free-standing wall extending parallel tothe sealing surface portions, the wall being aligned at the acute anglein relation to the longitudinal axis.
 3. A bottle attachment apparatusaccording to claim 2, wherein the valve block and each valve insert areformed of an injection molded plastic.
 4. A bottle attachment apparatusaccording to claim 2, wherein the plastic of the valve block and theplastic of each valve insert have a tensile strength in excess of 12 MPaat 120° C. (EN ISO 12086), and wherein the plastic of the valve blockhas a tensile strength (EN ISO 12086 measured at 23° C.) which is higherby 40% to 100% than the plastic of each valve insert.
 5. A bottleattachment apparatus as claimed in claim 2, wherein the stop portion oneach valve insert is disposed on a front end of the valve insert whichis located in the respective valve receptacle, wherein the sealingportion adjoins the stop portion and is disposed in the direction of anopposite, rear end of the valve insert, and wherein the fasteningportion adjoins the sealing portion and is disposed in a directiontoward the rear end of the valve insert.
 6. A bottle attachmentapparatus as claimed in claim 2, wherein each valve insert is sealed, asviewed in cross section in a plane extending along the length of theexhaust line and valve receptacle, against the respective valvereceptacle by the stop portion and the sealing portion without thepresence of any circumferentially extending seal elements.
 7. A bottleattachment apparatus as claimed in claim 2, wherein the sealingportions, when abutting on one another, are deformed.
 8. The valve blockassembly as claimed in claim 2, wherein a hollow chamber is located inthe valve block behind the wall.
 9. The valve block assembly as claimedin claim 2, wherein the valve block assembly comprises a push-fitconnector for an intake line that is disposed at a rear end of theintake valve insert.